Microlithography Adhesion

Superior Micro / Nano Resist Adhesion for Advanced Lithography

SurPass microlithography adhesion promoters provide excellent resist adhesion on a broad range of substrate materials. Increased adhesion is acheived through cationic modification of the substrate surface energy without depositing a film or altering the substrate chemisty and is easily applied by spin coat, immersion or spray applications. SurPass is waterborne and non-hazardous.

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Download the SurPass Technical Data Sheet

SurPass demonstrates excellent adhesion properties on a wide range of substrate materials, including glass, silicon nitride, metals, metal oxides, ceramics (ruby, sapphire) and plastics (PET). SurPass is compatible with most positive and negative resist and polymer formulations, providing excellent adhesion when used in conjunction phenolformaldehyde resins (DNQ/Novolac), poly methyl methacrylate (PMMA), poly methylglutarimide (PMGI), epoxy based polymer (SU8), polyimide, electron beam and chemically amplified resists.

In addition to promoting adhesion, SurPass modifies the available surface energy to provide a more uniform coating surface for improved resist flow . Evidence suggests that SurPass may be used in polyimide processing to both improve performance and reduce material consumption through reduced Zeta potential. SurPass provides improved coating flow and uniformity even where resist / polymer adhesion is not an issue.

SurPass is manufactured in two versions designated as SurPass 3000 and SurPass 4000. SurPass 3000 is mildly acidic (3.0-3.5) and contains a cleaning and surfactant package for enhanced performance. SurPass 4000 is slightly alkaline (9.0-9.5) and contains no additives. Both versions are waterborne and non-hazardous. Unlike silanes (HMDS), SurPass is not limited to Si-substrates materials. No ammonia or breakdown products are formed during application. Both versions of SurPass are waterborne, non-hazardous, and contain no volatile organic compounds (VOC’s).

Publications

Reduced Zeta potential through use of cationic adhesion promoter for improved resist process performance and minimizing material consumption

Electron dose reduction through improved adhesion by cationic organic material with HSQ resist on an InGaAs multilayer system on GaAs substrate

Improved Adhesion by Surfscan for 30nm HSQ Column Arrays on a InGaAs / GaAs Multilayer System (presentation)

Improved adhesion of novolac and epoxy based resists by cationic organic materials on critical substrates for high volume patterning applications

Metal Free Seedless Adhesion of Au on Si Native Oxide

FAQs

1. What does DisChem, Inc. specialize in?

DisChem, Inc. develops and supplies specialty chemical solutions for microlithography, electron beam lithography, optical media, and electroforming processes. The company is recognized for precision-focused formulations that improve adhesion, minimize defects, and enhance process reliability in advanced micro- and nano-fabrication environments.

Adhesion directly impacts pattern stability throughout coating, exposure, and development stages. Poor adhesion can lead to resist lifting, pattern distortion, or collapse. Strong adhesion ensures accurate pattern transfer, improved yields, and consistent performance across complex micro- and nano-scale substrates.

SurPass is a waterborne, cationic adhesion promoter designed to improve resist bonding to various substrates. Applied before resist coating, it modifies surface energy to enhance adhesion without permanently altering substrate chemistry or interfering with subsequent lithographic processing steps.

SurPass forms a thin cationic layer that increases surface energy and promotes resist attachment. Unlike aggressive treatments, it does not etch, roughen, or chemically alter the substrate, preserving surface integrity while delivering reliable and uniform adhesion performance.

SurPass is compatible with a wide range of substrates including glass, silicon, silicon nitride, metal oxides, metals, ceramics such as sapphire, and select polymers like PET. This broad compatibility supports diverse research, development, and manufacturing lithography applications.

SurPass differs from solvent-based or silane adhesion promoters by being waterborne, non-hazardous, and free of VOCs. It delivers consistent adhesion across multiple substrates while reducing safety risks, environmental impact, and process complexity associated with conventional adhesion methods.

SurPass 3000 is mildly acidic and includes surfactant and cleaning functionality, while SurPass 4000 is slightly alkaline and additive-free. Both formulations are cationic and waterborne, allowing users to select the best option for their specific substrate and process needs.

Yes, SurPass is compatible with a broad range of resist chemistries, including both positive and negative resists. It has demonstrated effectiveness with PMMA, SU-8, DNQ/Novolac systems, and other commonly used resists in microlithography and e-beam lithography.

By modifying surface energy, SurPass improves resist wetting and flow during spin coating. This results in more uniform films, fewer coating defects, and improved critical dimension control, particularly on substrates with challenging or low surface energy characteristics.

SurPass formulations are waterborne, non-hazardous, and free of volatile organic compounds and ammonia. This makes them safer for operators, easier to store, and more environmentally responsible compared to many traditional adhesion promoters used in lithographic processes.

Improved adhesion achieved with SurPass can result in more stable resist patterns during exposure and development. In certain applications, this enhanced stability has enabled reduced electron beam exposure doses while maintaining resolution and pattern fidelity.

In many processes, SurPass can reduce or eliminate the need for dehydration baking or solvent pre-wetting steps. This streamlines workflows, shortens processing time, and reduces chemical usage without compromising adhesion or lithographic performance.

Stronger adhesion minimizes resist lifting, peeling, and pattern distortion during development. By reducing defects and rework, SurPass improves process repeatability and overall yield, which is essential for high-precision micro- and nano-fabrication applications.

Yes, SurPass can improve adhesion between substrates and evaporated metals. This is particularly valuable in metallization and electroforming applications where strong metal-to-substrate bonding is critical for mechanical stability and downstream processing reliability.

SurPass is widely used in research laboratories and production environments. Its ease of application, consistent results, and broad substrate compatibility make it ideal for prototyping, process development, and scalable manufacturing workflows.

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